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Brookhart's acid : ウィキペディア英語版
Brookhart's acid

Brookhart's acid is the salt of the diethyl ether oxonium ion and tetrakis[3,5-bis(trifluoromethyl)phenyl)borate (BAr’4). It is a colorless solid, used as a strong acid. The compound was first reported by Volpe, Grant, and Brookhart in 1992.
==Preparation==
This compound is prepared by treatment of NaBAr’4 in diethyl ether (Et2O) with hydrogen chloride:
: NaBAr'4 + HCl + 2 Et2O → ()+BAr'4 + NaCl
NaBAr’4 is soluble in diethyl ether, whereas sodium chloride is not. Precipitation of sodium chloride thus drives the formation of the oxonium acid compound, which is isolable as a solid.〔

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